Key Takeaways for Atomic Structure & Radioactivity
1. Atomic Structure
Key Components
- Protons: Positively charged (+1), found in the nucleus.
- Neutrons: Neutral (0 charge), found in the nucleus.
- Electrons: Negatively charged (-1), orbit the nucleus.
- Nucleus: Contains protons and neutrons; radius ≈ 10−1510−15 m.
- Atom: Overall neutral (protons = electrons).
Atomic & Mass Numbers
- Atomic Number (ZZ): Number of protons (defines the element).
- E.g., Carbon: Z=6Z=6 → 6 protons.
- Mass Number (AA): Protons + neutrons.
- E.g., Carbon-14: A=14A=14 → 6 protons + 8 neutrons.
Isotopes
- Atoms of the same element with different neutrons.
- E.g., Carbon-12 (126C126C) vs. Carbon-14 (146C146C).
Example Calculation:
- Lithium atom: 3 protons, 4 neutrons.
- Atomic number (ZZ) = 3.
- Mass number (AA) = 3 + 4 = 7.
2. Nuclear Radiation
Types & Properties
Radiation | Nature | Ionising Power | Penetration | Range in Air |
---|---|---|---|---|
Alpha (α) | Helium nucleus (24He24He) | High | Stopped by paper | ~5 cm |
Beta (β) | High-speed electron (−10e−10e) | Medium | Stopped by aluminium | ~1 m |
Gamma (γ) | Electromagnetic wave | Low | Reduced by lead | Several km |
Neutron | Neutral particle | High (indirect) | Stopped by concrete | Long |
Decay Equations
- Alpha Decay:
92238U→90234Th+24He92238U→90234Th+24He- Mass ↓4, Atomic ↓2.
- Beta Decay:
614C→714N+−10e614C→714N+−10e- Mass same, Atomic ↑1 (neutron → proton + electron).
- Gamma Decay: No change in mass/atomic number.
Tip: Balance equations by ensuring mass and atomic numbers are equal on both sides.
3. Half-Life & Radioactive Decay
- Half-Life (t1/2t1/2): Time for half the nuclei in a sample to decay.
- Random Process: Cannot predict when a single nucleus will decay.
Example Calculation:
- A sample has an initial activity of 160 Bq. After 2 half-lives:
- 160→80→40160→80→40 Bq.
Graph Tip: Plot count rate vs. time. The half-life is the time taken for the count rate to halve.
4. Uses of Radioactivity
- Medical Tracers:
- E.g., Technetium-99 (γ emitter, t1/2t1/2 = 6 hours) for imaging organs.
- Radiotherapy:
- Gamma rays target cancerous cells.
- Sterilisation:
- Gamma rays kill bacteria on medical equipment.
Safety: Use tongs, lead shielding, and monitor doses with film badges.
5. Hazards & Safety
- Ionisation: Radiation removes electrons from atoms, damaging cells.
- Dose Measurement: In sieverts (Sv).
- 1 mSv = 1100010001 Sv.
- Background Radiation: Natural sources (radon gas, cosmic rays) contribute ~2.4 mSv/year in the UK.
Key Risk: Alpha particles are most dangerous if ingested (e.g., radon gas in lungs).
6. Nuclear Fission & Fusion
Fission
- Process: Splitting heavy nuclei (e.g., 92235U92235U) → energy + neutrons.
92235U+01n→56141Ba+3692Kr+301n+energy92235U+01n→56141Ba+3692Kr+301n+energy - Chain Reaction: Neutrons trigger further fission (controlled in reactors).
Fusion
- Process: Combining light nuclei (e.g., hydrogen → helium).
- Occurs in stars.
211H→12H+energy211H→12H+energy
- Occurs in stars.
Key Difference:
- Fission releases energy from heavy atoms; fusion from light atoms.
Exam Tips
- Equations: Always balance mass and atomic numbers.
- Half-Life: Use Remaining=Initial×(12)nRemaining=Initial×(21)n, where nn = number of half-lives.
- Radiation Properties: Memorise penetration/ionising power (alpha = paper, beta = aluminium, gamma = lead).
- Safety: Explain shielding methods (e.g., lead for gamma).
Common Mistake: Confusing neutron emission (mass ↓1, atomic same) with beta decay (atomic ↑1).
Example Question:
“A sample of iodine-131 (t1/2t1/2 = 8 days) has an activity of 800 Bq. What is its activity after 24 days?”
Solution:
24 days = 3 half-lives.
800→400→200→100800→400→200→100 Bq.
50 GCSE Questions on Atomic Structure & Radioactivity
Questions
- Atomic Structure:
a) Name the three subatomic particles in an atom and state their charges.
b) What is the approximate radius of an atom?
c) How does the radius of a nucleus compare to the radius of an atom? - Isotopes:
a) Define the term isotope.
b) Carbon-12 and Carbon-14 are isotopes. How do their atomic structures differ? - Atomic & Mass Numbers:
a) An atom has 6 protons and 8 neutrons. Calculate its mass number.
b) The atomic number of sodium is 11. How many electrons does a neutral sodium atom have? - Nuclear Radiation:
a) List the four types of nuclear radiation.
b) Which type of radiation has the highest ionising power? - Alpha Decay:
a) Write the equation for the alpha decay of Uranium-238 (92238U92238U).
b) How do the mass and atomic numbers change during alpha decay? - Beta Decay:
a) Write the equation for the beta decay of Carbon-14 (614C614C).
b) Explain why beta decay increases the atomic number by 1. - Gamma Radiation:
a) Why does gamma decay not change the mass or atomic number of a nucleus?
b) State one use of gamma radiation in medicine. - Neutron Emission:
a) Write the equation for the neutron emission of Helium-5 (25He25He).
b) How does neutron emission affect the mass number? - Ionisation:
a) Explain how alpha particles ionise atoms.
b) Why is ionisation harmful to living cells? - Geiger-Müller Tube:
a) What is the purpose of a Geiger-Müller (GM) tube?
b) Define background radiation. - Penetration Power:
a) Which material stops gamma radiation: paper, aluminium, or lead?
b) Why can alpha particles be stopped by paper? - Half-Life:
a) Define half-life.
b) A sample has a half-life of 5 years. What fraction remains after 15 years? - Carbon Dating:
a) Explain how carbon-14 is used to determine the age of ancient artifacts.
b) Why is carbon dating unreliable for objects older than 50,000 years? - Radiation Dose:
a) What unit is used to measure radiation dose?
b) A dose of 4 Sv is considered fatal. Convert 4000 mSv to Sv. - Medical Tracers:
a) Why is technetium-99 used as a medical tracer?
b) State two properties that make it suitable for this use. - Radiotherapy:
a) How are gamma rays used in cancer treatment?
b) Why is a high dose of radiation dangerous even in targeted therapy? - Irradiation vs Contamination:
a) Distinguish between irradiation and contamination.
b) Why is contamination more hazardous than irradiation? - Nuclear Fission:
a) Define nuclear fission.
b) Write the equation for the fission of Uranium-235 (92235U92235U) into Barium-141 (56141Ba56141Ba) and Krypton-92 (3692Kr3692Kr). - Chain Reaction:
a) What is a chain reaction in nuclear fission?
b) How do control rods in a nuclear reactor regulate this process? - Nuclear Fusion:
a) Define nuclear fusion.
b) Why is fusion difficult to achieve on Earth? - Rutherford’s Experiment:
a) Describe how Rutherford’s gold foil experiment disproved the plum pudding model.
b) What conclusion did Rutherford draw about the structure of the atom? - Bohr Model:
a) How did Bohr’s model improve upon Rutherford’s?
b) What happens when an electron absorbs electromagnetic radiation? - Plum Pudding Model:
a) Describe the plum pudding model of the atom.
b) Why was it replaced? - Background Radiation:
a) List three natural sources of background radiation.
b) Why is radon gas a significant hazard? - Radiation Protection:
a) Why do nuclear workers wear film badges?
b) What safety precautions should be taken when handling alpha sources?
Detailed Answers
- Atomic Structure:
a) Protons (+1), neutrons (0), electrons (-1).
b) Radius ≈ 10−1010−10 m.
c) The nucleus is about 110,00010,0001 the size of the atom. - Isotopes:
a) Isotopes are atoms of the same element with the same number of protons but different numbers of neutrons.
b) Carbon-12 has 6 neutrons; Carbon-14 has 8 neutrons. - Atomic & Mass Numbers:
a) Mass number = 6 + 8 = 14.
b) Electrons = protons = 11. - Nuclear Radiation:
a) Alpha, beta, gamma, neutron.
b) Alpha particles (high ionisation due to large mass and charge). - Alpha Decay:
a) 92238U→90234Th+24He92238U→90234Th+24He
b) Mass ↓4, atomic ↓2. - Beta Decay:
a) 614C→714N+−10e614C→714N+−10e
b) A neutron converts to a proton (↑ atomic number by 1) and emits an electron. - Gamma Radiation:
a) Gamma rays are electromagnetic waves; they only remove energy, not particles.
b) Sterilising medical equipment or cancer treatment. - Neutron Emission:
a) 25He→24He+01n25He→24He+01n
b) Mass number ↓1; atomic number unchanged. - Ionisation:
a) Alpha particles collide with atoms, knocking off electrons and creating ions.
b) Ions disrupt chemical reactions in cells, causing mutations or cell death. - Geiger-Müller Tube:
a) Detects ionising radiation by counting particles entering the tube.
b) Background radiation is natural radiation from rocks, cosmic rays, etc. - Penetration Power:
a) Lead.
b) Alpha particles are large and highly charged, losing energy quickly. - Half-Life:
a) Time taken for half the radioactive nuclei in a sample to decay.
b) 1881 remains (3 half-lives: 12→14→1821→41→81). - Carbon Dating:
a) Living organisms absorb carbon-14. After death, it decays. By measuring remaining 14C14C, age is calculated.
b) Too little 14C14C remains to measure accurately. - Radiation Dose:
a) Sieverts (Sv).
b) 4000 mSv=4 Sv4000mSv=4Sv. - Medical Tracers:
a) Emits gamma rays (detectable outside the body) and has a short half-life (6 hours).
b) Low ionisation, short half-life. - Radiotherapy:
a) Gamma rays destroy cancer cells by ionising their DNA.
b) High doses damage healthy cells, causing side effects. - Irradiation vs Contamination:
a) Irradiation: Exposure to radiation externally. Contamination: Radioactive material enters the body.
b) Contamination exposes internal organs to prolonged radiation. - Nuclear Fission:
a) Splitting a heavy nucleus into smaller nuclei, releasing energy.
b) 92235U+01n→56141Ba+3692Kr+301n+energy92235U+01n→56141Ba+3692Kr+301n+energy - Chain Reaction:
a) Neutrons from fission trigger further fission events.
b) Control rods absorb excess neutrons to slow the reaction. - Nuclear Fusion:
a) Combining light nuclei to form a heavier nucleus, releasing energy.
b) Requires extremely high temperatures/pressure (like in stars). - Rutherford’s Experiment:
a) Most alpha particles passed through, but some deflected, indicating a small, dense nucleus.
b) Atoms have a tiny, positively charged nucleus surrounded by empty space. - Bohr Model:
a) Electrons orbit in fixed energy levels, explaining atomic spectra.
b) Electron moves to a higher energy level (excited state). - Plum Pudding Model:
a) A “sea” of positive charge with electrons embedded.
b) It couldn’t explain alpha particle scattering results. - Background Radiation:
a) Radon gas, cosmic rays, rocks, food.
b) Radon emits alpha particles; inhaled, it damages lung tissue. - Radiation Protection:
a) To monitor cumulative radiation exposure.
b) Use tongs, avoid ingestion, store in lead containers.